Preparation and Ion Transport Properties of a New TiO2 Dispersed Sodium Ion Conducting Nanocomposite Polymer Electrolytes

Russian Journal of Electrochemistry - Preparation and ion transport property of new Na+ ion conducting nanocomposite polymeric electrolytes (NCPEs): (1 – x)[80PEO:20NaI] + xTiO2, where 0...     

Strongly enhanced pinning force density in YBCO–BaTiO3 nanocomposite superconductor

YBa₂Cu₃O_7−δ–BaTiO₃ (4 wt.%) (YBCO–BTO (4%)) composite bulk polycrystalline sample has been synthesized by solid state reaction method. The structure of composite sample has been investigated by X-ray diffraction and magnetization measurements were carried out using MPMS SQUID VSM. The superconducting transition temperature of the YBCO–BTO (4%) sample was similar to that of pure YBCO. The critical current density (J_c) for YBCO–BTO (4%) sample increases significantly as compared to pure YBCO sample. The enhancement of the critical current density in the YBCO–BTO (4%) sample has been attributed to the presence of BaTiO₃ nanoparticles acting as artificial pinning centres. The introduction of BaTiO₃ particles in YBCO increases pinning force density from 0.71 GN/m² to 1.41 GN/m² at 4 K and 0.33 MN/m² to 0.97 MN/m² at 77 K.     

A model for expansion ratio in liquid-solid fluidized beds

Liquid-solid fluidized beds are used in mineral processing industries to separate particles based on parti- cle size, density, and shape. Understanding the expanded fluidized bed is vital for accurately assessing its performance. Expansion characteristics of the fluidized bed were studied by performing several experi- ments with iron ore, chromite, quartz, and coal samples. Using water as liquid medium, experiments were conducted to study the effects of particle size, particle density, and superficial velocity on fluidized bed expansion. The experimental data were utilized to develop an empirical mathematical model based on dimensional analysis to estimate the expansion ratio of the fluidized bed in terms of particle character- istics, operating and design parameters. The predicted expansion ratio obtained from the mathematical model is in good agreement with the experimental data.     

Ligand Effect on Physicochemical Properties of Ionic Liquid

In the solvent extraction process, the importance of an extractant (or ligand) and a diluent is inferred from their respective physicochemical properties. We have brought together all the recent results reported on the mixture of different extractants dissolved in a well-known ionic liquid diluent: 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C₄mim][NTf₂]) in the form of a review and aimed to emphasize the role of ligand polarity and structure on the physicochemical properties of an ionic liquid (IL) diluent. Some of the most important properties such as dynamic viscosity (η), absolute density ( ), energy of activation (E_a), coefficient of thermal expansion (α), phase separation time (PST), refractive index (n), etc., have been discussed meticulously in the paper. The effect of ligand structure on the aggregation behaviour of IL phase and the physicochemical properties of gamma irradiated solvent phases containing different ligands and their solution with IL phase also have been deliberated in detail.